Dokumente Fakultät für Chemie (inkl. GAUSS) nach Gutachter "Schulzke, Carola Prof. Dr."
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Molybdenum and tungsten compounds with dithiolene ligands inspired by molybdopterin as models for the molybdenum and tungsten cofactors
(2011-11-22)This thesis deals with the bio-inorganic chemistry of molybdenum and tungsten. Various synthetic methodologies have been developed to prepare the model complexes of molybdenum and tungsten ... -
Pyrazolat-liganden mit zwei facial tridentaten Koordinationstaschen - Metallkomplexe und erste Reaktivitätsuntersuchungen
(2007-12-11)In the aim of synthesis of model complexes for active core of type 3 copper proteins a novel ligand system was developed. Chief characteristic are two facial tridentate coordination pockets ... -
Syntheses, Structures, Electrochemical and Oxygen Atom Transfer Properties of Molybdenum and Tungsten Complexes with Sulfur and Selenium Containing Ligands
(2007-05-10)Molybdenum and tungsten can be found at the active sites of the molybdopterin-containing oxygen-atom-transfer enzymes. Another interesting diversity of these enzymes is that in the DMSO ... -
Verbindungen von Molybdän und Wolfram in den Oxidationsstufen IV - VI als Modelle für Molybdän- und Wolfram-Cofaktoren
(2011-01-27)This thesis includes the synthesis of model compounds for molybdenum- and tungsten cofactors. Comparative studies of the pairs were done to show similarities and differences. Especially the ...