Merging Electrosynthesis with 3d Transition Metal-Catalyzed C–H Transformations

Meyer, Tjark Hannes

dc.contributor.advisor	Ackermann, Lutz Prof. Dr.
dc.contributor.author	Meyer, Tjark Hannes
dc.date.accessioned	2021-07-12T08:25:50Z
dc.date.available	2021-07-19T00:50:06Z
dc.date.issued	2021-07-12
dc.identifier.uri	http://hdl.handle.net/21.11130/00-1735-0000-0008-58A0-0
dc.identifier.uri	http://dx.doi.org/10.53846/goediss-8723
dc.language.iso	eng	de
dc.rights.uri	http://creativecommons.org/licenses/by-nc-nd/4.0/
dc.subject.ddc	540	de
dc.title	Merging Electrosynthesis with 3d Transition Metal-Catalyzed C–H Transformations	de
dc.type	doctoralThesis	de
dc.contributor.referee	Ackermann, Lutz Prof. Dr.
dc.date.examination	2021-06-28
dc.description.abstracteng	In recent years, oxidative C–H transformations have emerged as increasingly powerful tools in molecular syntheses. However, despite great progress towards more atom and step economic synthetic methods, oxidative couplings largely rely on precious metal catalysts and stoichiometric amounts of toxic metal oxidants, which compromises the overall sustainability of the C–H activation strategy. Within this thesis, this contradiction was resolved by the direct merger of electrochemistry with 3d metal-catalyzed C–H activation, thus setting the stage for organic syntheses at a unique level of resource economy. The novel metallaelectrocatalysis was employed for the traceless formation of various C–C or C–Het bonds. In addition, the mechanisms of these reactions were investigated by detailed mechanistic studies, uncovering, among others, novel mechanistic scenarios to be effective within cobaltaelectrocatalysis.	de
dc.contributor.coReferee	Das, Shoubhik Prof. Dr.
dc.contributor.thirdReferee	Koszinowski, Konrad Prof. Dr.
dc.contributor.thirdReferee	Walker, Johannes C. L. Prof. Dr.
dc.contributor.thirdReferee	Frauendorf, Holm Dr.
dc.contributor.thirdReferee	Janßen-Müller, Daniel Dr.
dc.subject.eng	Electrochemistry	de
dc.subject.eng	Electrocatalysis	de
dc.subject.eng	Transition Metal Catalysis	de
dc.subject.eng	C-H Activation	de
dc.subject.eng	Renewable Energy	de
dc.subject.eng	Cobalt	de
dc.subject.eng	Manganese	de
dc.subject.eng	Reaction mechanism	de
dc.identifier.urn	urn:nbn:de:gbv:7-21.11130/00-1735-0000-0008-58A0-0-1
dc.affiliation.institute	Fakultät für Chemie	de
dc.subject.gokfull	Chemie (PPN62138352X)	de
dc.description.embargoed	2021-07-19
dc.identifier.ppn	1762719932

Dateien

Name:Diss_Tjark_H_Meyer.pdf

Größe:30.02Mb

Format:PDF

Öffnen

Name:: Diss_Tjark_H_Meyer.pdf
Größe:: 30.02Mb
Format:: PDF

Öffnen

Das Dokument erscheint in:

Fakultät für Chemie (inkl. GAUSS) [702]

Zur Kurzanzeige