Electrochemical C-H Activations with 3d and 4d Transition Metal Catalysts

Massignan, Leonardo

dc.contributor.advisor	Ackermann, Lutz Prof. Dr.
dc.contributor.author	Massignan, Leonardo
dc.date.accessioned	2021-12-20T15:39:31Z
dc.date.available	2021-12-27T00:50:08Z
dc.date.issued	2021-12-20
dc.identifier.uri	http://hdl.handle.net/21.11130/00-1735-0000-0008-59CE-D
dc.identifier.uri	http://dx.doi.org/10.53846/goediss-9013
dc.identifier.uri	http://dx.doi.org/10.53846/goediss-9013
dc.language.iso	eng	de
dc.publisher	Niedersächsische Staats- und Universitätsbibliothek Göttingen	de
dc.rights.uri	http://creativecommons.org/licenses/by-nc-nd/4.0/
dc.subject.ddc	540	de
dc.title	Electrochemical C-H Activations with 3d and 4d Transition Metal Catalysts	de
dc.type	doctoralThesis	de
dc.contributor.referee	Ackermann, Lutz Prof. Dr.
dc.date.examination	2021-12-02
dc.description.abstracteng	The oxidative metal-catalyzed C–H activation of inert bonds is a powerful tool for the functionalization of complex molecules. This platform allowed the broadening of the organic chemists’ toolbox and improved the resource-economy of synthetic routes, avoiding prefunctionalizations of starting materials. Nevertheless, its applications were constrained by the use of stoichiometric oxidants, which limited the sustainability of this approach. In contrast, the use of electricity as environmental-friendly and versatile oxidant enhanced the sustainability of oxidative metal-catalyzed C–H activation and opened the way to the study of novel reactivities and selectivities. Within this thesis, electrochemical cobalt catalyzed and ruthenium catalyzed annulation reactions were initially studied. The electrochemical approach was then broadened to the C–H oxygenation reactions with ruthenium catalysis enabled by electrogenerated hypervalent iodine species and with rhodium catalysis. In addition, C–H arylation and C–H alkylation reaction by earth-abundant manganese as catalyst and electricity as sustainable oxidant was developed.	de
dc.contributor.coReferee	Breder, Alexander Prof. Dr.
dc.contributor.thirdReferee	Tietze, Lutz Prof. Dr. Dr. H.c.
dc.contributor.thirdReferee	Alcarazo, Manuel Prof. Dr.
dc.contributor.thirdReferee	John, Michael Dr.
dc.contributor.thirdReferee	Janßen-Müller, Daniel Dr.
dc.subject.eng	C–H Activation	de
dc.subject.eng	Transition Metal Catalysis	de
dc.subject.eng	Electrochemistry	de
dc.subject.eng	Ruthenium	de
dc.subject.eng	Rhodium	de
dc.subject.eng	Manganese	de
dc.subject.eng	Cobalt	de
dc.subject.eng	Hypervalent iodine	de
dc.identifier.urn	urn:nbn:de:gbv:7-21.11130/00-1735-0000-0008-59CE-D-8
dc.affiliation.institute	Fakultät für Chemie	de
dc.subject.gokfull	Chemie (PPN62138352X)	de
dc.description.embargoed	2021-12-27
dc.identifier.ppn	1782630406

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Name:: Dissertation - L. Massignan.pdf
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Beschreibung:: Doctoral Dissertation - L. ...

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Fakultät für Chemie (inkl. GAUSS) [701]

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