Control over assembly and interpenetration of Pd-based coordination cages

by Rongmei Zhu
Doctoral thesis
Date of Examination:2017-03-24
Date of issue:2017-03-27
Advisor:Prof. Dr. Guido Clever
Referee:Prof. Dr. Guido Clever
Referee:Prof. Dr. Franc Meyer
Persistent Address: http://dx.doi.org/10.53846/goediss-6196

 

 

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Abstract

English

In the first part, a thermordynamically stable monomeric cage was obtained and the transformation from the monomeric cage to dimeric cage and even to a triple catenane was realized by varying the amount of halide anions. In the second part, a peanut-shape cage and its interpenetration cage were obtained by elongating the backbones. In the last part, two multi-component heteroleptic coordination cages were achieved from two different ligands via side-chain directed complimentary coordination strategy.
Keywords: supramolecular; coordination cage; self-assembly; palladium
 
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