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dc.contributor.advisor Meyer, Franc Prof. Dr.
dc.contributor.author Dalle, Kristian Erwin
dc.date.accessioned 2016-10-10T14:16:24Z
dc.date.available 2016-10-10T14:16:24Z
dc.date.issued 2016-10-10
dc.identifier.uri http://hdl.handle.net/11858/00-1735-0000-002B-7C1A-B
dc.language.iso eng de
dc.publisher Niedersächsische Staats- und Universitätsbibliothek Göttingen de
dc.rights.uri http://creativecommons.org/licenses/by-nc-nd/4.0/
dc.subject.ddc 540 de
dc.title Bioinspired Activation of Oxygen with Pyrazole-Supported Dinuclear Copper Complexes de
dc.type doctoralThesis de
dc.contributor.referee Meyer, Franc Prof. Dr.
dc.date.examination 2014-10-22
dc.description.abstracteng A series of compartmental pyrazole-bridging ligands were successfully used to gain insights into copper-mediated dioxygen activation chemistry, and thus expand on the proven potential of these organic scaffolds for emulating features of dinuclear metallobiosites. Several systems were investigated in detail, leading to identification of a novel type of peroxo-dicopper(II) adduct. Crystallographic structural determination revealed an unprecedented cis-μ-1,2-peroxide binding mode of the dioxygen-derived ligand. This in turn results in properties consistent with a computationally proposed enzymatic mechanism for dioxygen activation, and allows for binding of alkali metal cations in both solution and the solid state. de
dc.contributor.coReferee Diederichsen, Ulf Prof. Dr.
dc.subject.eng Dinuclear Copper, cis-Peroxo, Pyrazole, Oxygen Activation de
dc.identifier.urn urn:nbn:de:gbv:7-11858/00-1735-0000-002B-7C1A-B-0
dc.affiliation.institute Fakultät für Chemie de
dc.subject.gokfull Chemie  (PPN62138352X) de
dc.identifier.ppn 869904396

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