Homogeneous and Heterogeneous Chelation-Assisted Ruthenium(II)-Catalyzed C–H Functionalizations
by Svenja Warratz
Date of Examination:2016-11-18
Date of issue:2017-01-03
Advisor:Prof. Dr. Lutz Ackermann
Referee:Prof. Dr. Lutz Ackermann
Referee:Prof. Dr. Konrad Koszinowski
Referee:Prof. Dr. Dietmar Stalke
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Abstract
English
Ruthenium(II)-catalyzed direct C–H functionalizations have emerged as a powerful tool for organic chemists to construct C–C and C–Het bonds. In order to rationally improve the efficiency of these methods a mechanistic understanding of the underlying reactions is crucial. Within this thesis, studies to delineate the mode of powerful C–H transformations have been performed and new methods based on the principles of green chemistry have been developed.
Keywords: C-H Functionalization; Ruthenium; Catalysis