dc.contributor.advisor | Stalke, Dietmar Prof. Dr. | |
dc.contributor.author | Köhne, Ingo | |
dc.date.accessioned | 2018-05-16T08:33:40Z | |
dc.date.available | 2018-05-16T08:33:40Z | |
dc.date.issued | 2018-05-16 | |
dc.identifier.uri | http://hdl.handle.net/11858/00-1735-0000-002E-E3E8-1 | |
dc.identifier.uri | http://dx.doi.org/10.53846/goediss-6870 | |
dc.language.iso | eng | de |
dc.publisher | Niedersächsische Staats- und Universitätsbibliothek Göttingen | de |
dc.rights.uri | http://creativecommons.org/licenses/by-nc-nd/4.0/ | |
dc.subject.ddc | 540 | de |
dc.title | Novel Bulky Bis(benzoxazol-2-yl)methane Ligands in s-Block Metal Coordination | de |
dc.type | doctoralThesis | de |
dc.contributor.referee | Stalke, Dietmar Prof. Dr. | |
dc.date.examination | 2018-04-06 | |
dc.description.abstracteng | This thesis focusses on the preparation of bulky, NacNac-like bis(benzoxazol-2-yl)methane ligand platforms and their introduction to s-block metal coordination. Special focus is put on the synthesis of group 2 halide and -amide precursor compounds for subsequent reduction with alkali-metal reducing agents. First attempts to obtain reduced Mg(I) dimers are presented. All obtained compounds are thoroughly characterized. Moreover, the unprecedented synthesis of a solely O-coordinated organopotassium complex is discussed in detail, which exhibits a pronounced stability against hydrolysis. | de |
dc.contributor.coReferee | Meyer, Franc Prof. Dr. | |
dc.subject.eng | metal organic chemistry | de |
dc.subject.eng | bulky bis(benzoxazol-2-yl)methanes | de |
dc.subject.eng | NacNac | de |
dc.subject.eng | s-block metal coordination | de |
dc.subject.eng | alkaline earth metals | de |
dc.subject.eng | ligand engineering | de |
dc.subject.eng | hydrolysis stable complexes | de |
dc.identifier.urn | urn:nbn:de:gbv:7-11858/00-1735-0000-002E-E3E8-1-5 | |
dc.affiliation.institute | Fakultät für Chemie | de |
dc.subject.gokfull | Chemie (PPN62138352X) | de |
dc.identifier.ppn | 1022344692 | |