Structure-Property Correlations in Luminescent Anthracene Derivatives

by Timo Schillmöller
Doctoral thesis
Date of Examination:2021-07-06
Date of issue:2022-02-17
Advisor:Prof. Dr. Dietmar Stalke
Referee:Prof. Dr. Dietmar Stalke
Referee:Prof. Dr. Sven Schneider
Persistent Address: http://dx.doi.org/10.53846/goediss-37

 

 

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Abstract

English

This thesis aims to investigate the structure-property relationship of luminescent Anthracene derivatives. For this purpose, the Anthracene fluorophore was functionalized in various positions and with different substituents. As a result, the occurring non-covalent interactions between the anthracene moieties could be varied over a broad range. With combined structural and photophysical studies, the influence of these weak interactions on the solid-state emission properties were investigated in detail. Especially, the formation of the Anthracene excimer in the solid-state was examined comprehensively. The correlations obtained in this work allow a deeper understanding of the solid-state photophysical properties of common organic fluorophores, which is helpful for potential optoelectronic applications.
Keywords: Anthracene; Excimer; Solid-State Luminescence; Structure-Property Relationship
 
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