dc.contributor.advisor | Stalke, Dietmar Prof. Dr. | |
dc.contributor.author | Lüert, Daniel | |
dc.date.accessioned | 2022-09-30T09:48:13Z | |
dc.date.available | 2022-10-07T00:50:11Z | |
dc.date.issued | 2022-09-30 | |
dc.identifier.uri | http://resolver.sub.uni-goettingen.de/purl?ediss-11858/14269 | |
dc.identifier.uri | http://dx.doi.org/10.53846/goediss-9466 | |
dc.language.iso | eng | de |
dc.subject.ddc | 540 | de |
dc.title | Synthesis and Magnetic Properties of Polyimidosulfur- and Bis(benzoxazolyl)methanide-ligated Complexes | de |
dc.type | doctoralThesis | de |
dc.contributor.referee | Stalke, Dietmar Prof. Dr. | |
dc.date.examination | 2022-09-01 | de |
dc.description.abstracteng | The properties of magnetic molecules are promising centerpieces in various fields of research directed toward novel technologies, ranging from quantum computing, high-density data storage systems, and medical imaging applications, to other electron spin techniques.
This work aims to generate two new approaches toward novel magnetic materials. The first focus will shine a light on the air-stable and easily tunable bis(benzoxazole-2-yl)methanide (Box) ligand family that was never employed in d- and f-metal chemistry before. Here, the goal is to establish air-stable benchmark systems of single-molecule magnets (SMMs), which allow profound studies of magneto structural correlations and qualify for high-resolution charge density experiments. Second, this thesis evaluates various alkali-metal-based triimidosulfites as versatile precursors for SMMs, demonstrating a linear coordination mode that is beneficial for fine-tuning the local anisotropy in such systems. A coordination mode with two ligands sandwiching one lanthanide ion is envisioned. Starting with the well-known lithium precursor [Li4{NtBu)3S2], the higher homologues with sodium and potassium are feasible and should provide fruitful chemistry. | de |
dc.contributor.coReferee | Meyer, Franc Prof. Dr. | |
dc.contributor.thirdReferee | Waitz, Thomas Prof. Dr. | |
dc.subject.eng | single-molecule magnet | de |
dc.subject.eng | triimidosulfites | de |
dc.subject.eng | lanthanides | de |
dc.subject.eng | dysprosium SMM | de |
dc.subject.eng | Bis(benzoxazolyl)methanes | de |
dc.subject.eng | transition metals | de |
dc.subject.eng | magnetism | de |
dc.subject.eng | cobalt SMM | de |
dc.subject.eng | sulfur-nitrogen | de |
dc.identifier.urn | urn:nbn:de:gbv:7-ediss-14269-4 | |
dc.affiliation.institute | Fakultät für Chemie | de |
dc.subject.gokfull | Chemie (PPN62138352X) | de |
dc.description.embargoed | 2022-10-07 | de |
dc.identifier.ppn | 1817928341 | |
dc.notes.confirmationsent | Confirmation sent 2022-09-30T10:15:01 | de |