dc.contributor.advisor | Meyer, Franc Prof. Dr. | |
dc.contributor.author | Vogel, Anastasia | |
dc.date.accessioned | 2017-02-14T09:27:06Z | |
dc.date.available | 2017-10-20T22:50:04Z | |
dc.date.issued | 2017-02-14 | |
dc.identifier.uri | http://hdl.handle.net/11858/00-1735-0000-002B-7D43-3 | |
dc.identifier.uri | http://dx.doi.org/10.53846/goediss-6119 | |
dc.language.iso | eng | de |
dc.publisher | Niedersächsische Staats- und Universitätsbibliothek Göttingen | de |
dc.rights.uri | http://creativecommons.org/licenses/by-nc-nd/4.0/ | |
dc.subject.ddc | 540 | de |
dc.title | The Siamese-Twin Porphyrin and its Metal Complexes: Platforms for Multi-Electron Redox Chemistry | de |
dc.type | doctoralThesis | de |
dc.contributor.referee | Meyer, Franc Prof. Dr. | |
dc.date.examination | 2016-10-21 | |
dc.description.abstracteng | This work comprises a redox-chemical investigation of a pyrazole-containing expanded porphyrin - the so-called Siamese-twin porphyrin. It includes synthetic organic and inorganic work and applies a series of analytical techniques. Repeated periphery-to-core fusion reactions of the ligand framework upon oxidation were studied in detail. Further, communication of the porphyrin-like hemi-macrocycles in a monopalladium(II) complex were revealed. Redox investigations and complementary calculations were performed to uncover the importance of a metalation-induced tautomerism on the electronic structure of the expanded porphyrin. Additional cooperative effects of the non-innocent ligands system and its central ion in bimetallic manganese(III) complexes were examined. | de |
dc.contributor.coReferee | Diederichsen, Ulf Prof. Dr. | |
dc.subject.eng | expanded porphyrins | de |
dc.subject.eng | oxidation | de |
dc.subject.eng | macrocycles | de |
dc.subject.eng | manganese | de |
dc.subject.eng | palladium | de |
dc.subject.eng | aromaticity | de |
dc.identifier.urn | urn:nbn:de:gbv:7-11858/00-1735-0000-002B-7D43-3-1 | |
dc.affiliation.institute | Fakultät für Chemie | de |
dc.subject.gokfull | Chemie (PPN62138352X) | de |
dc.description.embargoed | 2017-10-20 | |
dc.identifier.ppn | 880190256 | |