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dc.contributor.advisor Meyer, Franc Prof. Dr.
dc.contributor.author Mitevski, Oliver
dc.date.accessioned 2017-02-14T09:33:28Z
dc.date.available 2017-10-17T22:50:04Z
dc.date.issued 2017-02-14
dc.identifier.uri http://hdl.handle.net/11858/00-1735-0000-002B-7D44-1
dc.language.iso eng de
dc.publisher Niedersächsische Staats- und Universitätsbibliothek Göttingen de
dc.rights.uri http://creativecommons.org/licenses/by-nc-nd/4.0/
dc.subject.ddc 540 de
dc.title New Derivatives and Iron Complexes of the Siamese-Twin Porphyrin de
dc.type doctoralThesis de
dc.contributor.referee Meyer, Franc Prof. Dr.
dc.date.examination 2016-10-18
dc.description.abstracteng Variation of the substitution pattern of the Siamese-twin porphyrin (STP), an expanded porphyrin incorporating two pyrazole moieties, identified a set of substituents that result in an optimized preparation of highly crystalline products. The substituents have only negligible electronic and structural influences on the free base macrocycles and their dicopper complexes. Additionally, a new class of dinuclear iron complexes of the Siamese-twin porphyrin has been established. The homo- and heterobimetallic iron complexes of the STP were structurally characterized and showed to be pure intermediate spin in EPR spectroscopy and magnetic susceptibility measurements but remarkably gave two doublets in Mößbauer spectroscopy. de
dc.contributor.coReferee Schneider, Sven Prof. Dr.
dc.subject.eng Porphyrinoids de
dc.subject.eng Expanded Porphyrin de
dc.subject.eng Mößbauer de
dc.subject.eng Intermediate Spin de
dc.subject.eng Iron Complexes de
dc.identifier.urn urn:nbn:de:gbv:7-11858/00-1735-0000-002B-7D44-1-3
dc.affiliation.institute Fakultät für Chemie de
dc.subject.gokfull Chemie  (PPN62138352X) de
dc.description.embargoed 2017-10-17
dc.identifier.ppn 880190272

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