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Investigations towards the design, synthesis and application of new sulfur-based transfer reagents

dc.contributor.advisorAlcarazo, Manuel Prof. Dr.
dc.contributor.authorWaldecker, Bernd
dc.date.accessioned2019-06-20T08:10:21Z
dc.date.available2019-06-20T08:10:21Z
dc.date.issued2019-06-20
dc.identifier.urihttp://hdl.handle.net/21.11130/00-1735-0000-0003-C138-4
dc.identifier.urihttp://dx.doi.org/10.53846/goediss-7521
dc.identifier.urihttp://dx.doi.org/10.53846/goediss-7521
dc.language.isoengde
dc.publisherNiedersächsische Staats- und Universitätsbibliothek Göttingende
dc.rights.urihttp://creativecommons.org/licenses/by-nc-nd/4.0/
dc.subject.ddc540de
dc.titleInvestigations towards the design, synthesis and application of new sulfur-based transfer reagentsde
dc.typedoctoralThesisde
dc.contributor.refereeAlcarazo, Manuel Prof. Dr.
dc.date.examination2019-05-02
dc.description.abstractengNew dibenzothiophenium-based alkynylation reagents were prepared and their versatile reactivity was demonstrated in reactions with benchmark C-, S-, N- and P-nucleophiles. Straightforward experiments applying 13C-labeled reagents were proceeded to give a first insight in the reaction mechanism of the transfer reaction. Furthermore, the reagents were directly compared with their commercially available EBX analogues highlighting them as powerful and safe alternative to hypervalent iodine reagents.de
dc.contributor.coRefereeAckermann, Lutz Prof. Dr.
dc.contributor.thirdRefereeStalke, Dietmar Prof. Dr.
dc.contributor.thirdRefereeDas, Shoubhik Dr.
dc.contributor.thirdRefereeThomas, Franziska Dr.
dc.contributor.thirdRefereeHansmann, Max Dr.
dc.subject.engsulfur chemistryde
dc.subject.engelectrophilic alkynylationde
dc.subject.engisotopic labelingde
dc.subject.engalkynesde
dc.identifier.urnurn:nbn:de:gbv:7-21.11130/00-1735-0000-0003-C138-4-1
dc.affiliation.instituteFakultät für Chemiede
dc.subject.gokfullChemie  (PPN62138352X)de
dc.identifier.ppn166774559X


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