In the past several decades, transition metal-catalyzed cross-coupling reactions proved to be of utmost importance within organic synthesis. However, required prefunctionalization of substrates remained as a major disadvantage ...

With the growing field of DNA technology there is an increasing demand for new modifications of DNA, which improve its versatility and promote the DNA as a fundamental scaffold for a wide field of applications like catalysis, ...

The advent of new synthetic strategies has enriched the synthetic organic chemistry to access molecules with tremendous complexity. In this context, transition metal-catalyzed C−H activation has emerged as a powerful tool ...

Transition metal-catalyzed cross-coupling reaction as one of the greatest chemical innovations of 20th century has to utilize stoichiometric amounts of prefunctionalized reagents. In comparison, the transition metal-catalyzed ...

Ruthenium catalyzed C-N, C-O and C-C formation is achieved by C-H activation. access to primary aminoketones leds to synthetic synthons for different heterocycles. removable and reusability was shown first time in C-O bond ...

The thesis contents methods for the ruthenium- and cobalt catalyzed C-H activation of arenes. Ruthenium(II) catalysis was used to alkenylate arylacetamides using acrylates or alkynes. Further, ruthenium-catalyzed C-H ...

Catalytic C−H functionalization has emerged as an economically-attractive and environmentally-benign alternative to conventional cross-coupling approaches. Thus, major efforts have been made on transformations of inert C–H ...

The main focus of this work was the development of new methodologies for the efficient and step-economical synthesis of biaryls cores by direct arylation through direct C–H bond cleavage. In this aim, the first ruthenium-catalyzed ...

Methods for the selective functionalization of otherwise inert C–H bonds have been recognized as a transformative tool in synthetic organic chemistry, with applications ranging from the synthesis of complex bioactive ...

The application of diselenides as catalysts for the oxidative functionalization of alkenes via selenium-pi-acid catalysis was researched. Besides a method for the diselenide-catalyzed formation of indoles relying on NFSI ...